DOI: 10.1051/jp2:1997155
J. Phys. II France 7 (1997) 729-741
Effect of Fluctuations on the Freezing of a Colloidal Suspension in an External Periodic Potential
J. Chakrabarti1 and Supurna Sinha21 Department of Physics, Indian Institute of Science, Bangalore 560 012, India
2 Jawaharlal Nehru Centre for Advanced Scientific Research and Centre for Theoretical Studies, Indian Institute of Science, Bangalore 560 012, India
(Received 20 August 1996, received in final form 4 February 1997, accepted 7 February 1997)
Abstract
We incorporate the effects of fluctuations in a density functional analysis of the freezing of a colloidal liquid in the presence
of an external potential generated by interfering laser beams. A mean-field treatment, using a density functional theory,
predicts that with the increase in the strength of the modulating potential, the freezing transition changes from a first
order to a continuous one via a tricritical point for a suitable choice of the modulating wavevectors. We demonstrate here that the continuous nature of the freezing transition at large values of the external potential
survives the presence of fluctuations. We also show that fluctuations tend to stabilize the liquid phase in the large
regime.
© Les Editions de Physique 1997