Numéro |
J. Phys. II France
Volume 3, Numéro 7, July 1993
|
|
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Page(s) | 961 - 969 | |
DOI | https://doi.org/10.1051/jp2:1993176 |
J. Phys. II France 3 (1993) 961-969
Determination of two-electron crystal field parameters in some neodymium compounds
M. Faucher1, O. K. Moune1 and D. Garcia21 ERS 70 du CNRS, PCM, Ecole Centrale, Grande Voie des Vignes, 92295 Chatenay-Malabry Cedex, France
2 SII, 83 Bd Vincent Auriol, 75013 Paris, France
(Received 14 January 1993, revised 15 March 1993, accepted 9 April 1993)
Abstract
Two-electron, fourth rank (
k=4), crystal field parameters are fitted for four neodymium compounds : LiYF
4 : Nd
3+, Nd
2O
2S, Y
2O
3 : Nd
3+ and Nd
2O
3, displaying a strong experimental/calculated discrepancy for the
2H
11/2 level. The final mean deviation for all the levels is 2 cm
-1 (20 %) lower than that attained with the standard (one-particle) theory. The compound parameters
involve odd and even combinations of
k1 and
k2. The geometrical dependence
(q) seems to indicate a drift towards a C
site symmetry caused by axial ligands. The diagonal matrix elements of the correlated crystal field are smaller than the
off-diagonal matrix elements except for twin terms.
71.70C
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