| Numéro |
J. Phys. II France
Volume 5, Numéro 8, August 1995
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|---|---|---|
| Page(s) | 1241 - 1253 | |
| DOI | https://doi.org/10.1051/jp2:1995179 | |
DOI: 10.1051/jp2:1995179
J. Phys. II France 5 (1995) 1241-1253
Department of Physics and Astronomy, University of Rochester, Rochester, New York 14627-0011, USA and Groupe de Physico-Chimie Théorique, E.S.P.C.I., 10 rue Vauquelin, 75231 Paris Cedex 05, France
© Les Editions de Physique 1995
J. Phys. II France 5 (1995) 1241-1253
Fluctuation Theory of Charged AB-Random Copolymers
Andrey V. DobryninDepartment of Physics and Astronomy, University of Rochester, Rochester, New York 14627-0011, USA and Groupe de Physico-Chimie Théorique, E.S.P.C.I., 10 rue Vauquelin, 75231 Paris Cedex 05, France
(Received 11 November 1994, revised 1 April 1995, accepted 13 April 1995)
Abstract
We study the behavior of symmetric AB random copolymer systems with equal numbers of positive and negative charges on the
chains near the point of microphase separation. In the framework of the one-loop (Hartree) approximation the phase diagram
of this class of copolymer system as function of the number of charged monomers is calculated. We find two different regimes
in which microphase structure is stabilized by the long-range Coulomb interaction between charged groups or by the presence
of the bonds between the A and B monomers that want to segregate into domains.
© Les Editions de Physique 1995